![]() ![]() 3-Methylation reduces the potential energy barrier mediating decay to the cation ground state, making it vanish and leading to a pathway that we expect will contribute to the fastest radiationless decay amongst all methylated uracil species studied to date. We find an effective 3-state conical intersection accessible for 3mUra +, which points towards an additional pathway for radiationless decay. ![]() Upon populating the cation manifold, a crossing is predicted featuring different topography compared to other methylated uracil species in this study. At the S 0 minimum, 3-methyl-uracil (3mUra) shows almost degenerate excited cation states. We find 3-methylation, an epigenetic modification in non-negligible amounts, shows the largest differences in photoionised decay of all three derivatives studied compared to uracil itself. We compare our results against those for uracil and 5-methyl-uracil (thymine) previously published. ![]() Here we model the events following photoionisation and electronic excitation in uracil, methylated in the 1′ and 3′ positions, using the correlated XMS-CASPT2 method. Once you're done, easily share it with friends and foes alike across social networks.Ĭan't find your game? Suggest a game or vote for it on our Ideas portal.UV and VUV-induced processes in DNA/RNA nucleobases are central to understand photo-damaging and photo-protecting mechanisms in our genetic material. Grab the clips you love most, give it a quick trim if you like, or move to the video editor to combine them into an epic collage. See the best (and not so best) moments, review your APM speed, and relive the game. Once the match is over, you can flip through your captured clips in the match timeline. While playing, the app automatically captures your best moments and biggest plays, as well as manually recording on demand. ![]() Outplayed is the ultimate video capturing app for gamers. ![]()
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